Handling noxious liquid chemicals in bulk got numerous difficulties.
Outlined below are some problems associated
with various cargo systems found in tankers.
There is a high risk of contamination when a
common pump is used for several chemical tanks,
if the system is not properly drained between
different cargoes.
Modern tankers are often
equipped with individual submersible cargo
pumps but if these are connected to common
or shared lines there is still a risk of
contamination.
There will normally be a drain cock near or on the cargo pump itself,
this drain cock should be opened to verify that the line has been properly drained
before pumping a different cargo. In addition most of these pumps are hydraulically
driven, damage oil seals can lead to hydraulic oil leakage into the cargo tank
contaminating sensitive cargoes.
On oil tankers it is normal to have a common cargo tank ventilation system. The
vapours from one cargo tanks can easily enter a different tank in the system. This may
result in cargo contamination or change the flash point of the product. Petroleum
products are classified into volatile and non-volatile cargoes. A cargo with a flash
point below 60°C is a volatile product and a cargo with a flash point above 60°C is a
non-volatile cargo (different rules apply to the handling of volatile and non-volatile
cargoes).
Diesel oil has a flash point of around 63°C and vapours from a volatile cargo
can easily change the flash point to below 60°C, causing the cargo to be re-classified.
Many lube oils and lube additives are heated during transport. Steam coils are
normally used for this purpose. A leaking heating coil can lead to water entering the
cargo tank and consequently contaminating the cargo. Laboratory tests should be
carried out on cargoes contaminated by water. It should be established whether the
water is fresh or salt water. Contamination caused by fresh water is most likely to be
caused by a leaking heating coil whereas salt water contamination would probably be
caused by a leaking tank hatch, in which case the hatch packing should be checked.
Chemical tankers are normally
constructed with completely
independent cargo systems. Each cargo
tank will have an independent pumping
and venting system.
Cargo
contamination in chemical tankers are
often caused by poor cleaning of cargo
tanks or pipe lines. Unfortunately many
chemicals are extremely sensitive to
contamination, just a few parts per
million of a previous cargo can
contaminate an entire shipment.
Many
cargo samples are taken during the loading of chemicals. When a cargo is
contaminated it must be established whether the cargo was effected prior to loading;
or during its transportation on board. Cargo transfer hoses may also contribute to
cargo contamination, therefore hoses should be properly cleaned in between different
cargoes.
Related Info:
Cargo unloading operation safety precautions
Liaison between ship and shore
Preparation for cargo operation
Preparing a cargo tank atmosphere PV valves operation and maintenance procedure
Ship shore safety checklist while alongside a terminal
Main Info pages!
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Chemical hazards |||
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Cargo documents
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Safe stability
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Cargo care
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Preparation for unloading
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Inert gas systems
|||Gas freeing
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Nitrogen handling
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Chemical handling Safe practice
|||Handling equipments
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Cargo & Ballast pumps
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Cargo tanks
|||Tank cleaning
|||Special cargoes
|||Spills emergencies
|||Fire protection
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