Fire prevention is one of the most essential safety measures on board a chemical tanker. If a fire occurs, the action taken in the first few moments is vital. The man on the spot should raise the alarm and assess the situation. The minimum requirements for any ship's fire fighting equipment are laid down by the flag administration. The regulations are generally based on the principles of the International Convention for the Safety of Life at Sea (SOLAS) and, for ships certified to carry dangerous chemicals, on the IMO Bulk Chemical Codes. It is essential to maintain equipment to a high standard.
Specialist training for crew members, in particular as required for chemical endorsement of officers' professional certificates,
should be supplemented by regular drills on board. Discipline is needed in the daily routines. Watch out for obvious things such as:
i) look out for all leaking flanges, valve and pump glands
ii) keep pump room bilges free from cargo spills
iii) see to it that steam pipe insulation does not get soaked with oil or cargo
iv) check cargo tank and pump room atmosphere for cargo vapours before starting any work there
v) do not steam a cargo tank simultaneously with washing
vi) use flame-proof lights in cargo tanks and pump rooms
vii) check pump glands and bearings regularly for heating
viii) cigarette lighters in the cargo tank area to be forbidden
ix) observe cargo vapour release during loading and take action if vapours reach accomodation areas
x) check cargo pump glands for heating
xi) take active part in safety-drills and get acquainted with all the safety equipment
xii) instruct newcomers on board on safety procedures
xiii) get to know your ship, cargo handling gear etc.
The formal responsibility for surveillance of the fire fighting equipment normally rests with the respective
National Authority, but is in some cases delegated to the Classification Society. It rests with the Owner and the
Master to keep all equipment in order and to provide additional means for any cargo not covered by the intent
of the Rules of the National Authority.
Fire requires a combination of three elements: fuel, oxygen and heat or a source of ignition, and chemicals need the same
combination in order to burn. The principal means of controlling and extinguishing a fire is to remove one or more of the
elements, either by removal of the fuel, by cooling, or by excluding a supply of oxygen (air). But in chemical fires, the source of
ignition may be heat from a reaction within the chemical itself or from a reaction after mixing chemicals. A supply of oxygen
may be released from the chemical through heating by the fire. So fire fighting will be made more difficult. Without doubt, the
best course is to prevent any fire occurring.
Some liquid chemicals have properties which necessitate fire fighting techniques that differ from those used on simple oil fires.
The following list indicates some of these properties:
• some chemicals are soluble in water and at certain concentrations may be flammable;
• chemicals which are soluble in water will generally destroy normal foam, so alcohol resistant or dual purpose foam is required;
• some chemicals are heavier than, and insoluble in, water: they can be smothered by a blanket of water, provided application is
gentle;
• some chemicals react with water to produce heat and thus give off increased amounts of flammable (and in some cases toxic)
gases;
• some chemicals evolve large volumes of toxic vapours when heated;
• some chemicals form otherwise unexpected toxic vapours when burning;
• the comparatively low auto-ignition temperature of some chemicals increases the chance of re-ignition.
The cargo data sheet for a chemical will draw attention to these unusual properties and indicate the correct fire fighting medium
and special precautions for fire fighters.
Summarized below are recommended fire fighting methods for modern chemical tankers:
Total flooding method for seagoing chemical tankers
Water extinguishing method for fire protection
Foam extinguishing method for chemical tankers
Dry powder fire extinguishing method
Related Info:
Controlling the atmosphere in cargo tanks with nitrogen supplied from shore
How to determine the level of a liquid in a chemical tank
Poisoning and required first aid treatment onboard
Controlling the atmosphere in cargo tanks with nitrogen supplied from shore
Static electricity -How they generate & required safety precautions
After tank cleaning gas freeing safety guideline
for chemical tankers
Draegar safety tube prior entering enclosed spaces
Preparations prior allowing personnel into cargo tanks / enclosed spaces
How to rescue injured or unconscious person from enclosed spaces
Preparations for hot work and safety precautions
Tank cleaning fatality- case study & lessons learned
Tank cleaning and posoning hazards
Testing of tanks and cargoes
Practical tank cleaning methods for various noxious liquid cargo
Special tank cleaning method
Determining proper tank cleaning by acid wash method
Supervision of all tank cleaning and gas freeing operations
Disposal of tank washings, slops and dirty ballast - safe method
Following reference publications provide useful guidance and international regulations for carrying hazardous chemicals at sea.
- SOLAS (latest consolidated edition)
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MARPOL – 73/78 (latest consolidated edition)
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BCH / IBC Code
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International Safety Guide for Oil Tankers and Terminals (ISGOTT)
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Tanker Safety Guide (Chemicals)
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Ship to Ship Transfer Guide (Petroleum)
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Safety in Oil Tankers
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Safety in Chemical Tankers
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IMDG Code
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Supplement to IMDG Code (Including MFAG and Ems)
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SOPEP
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Clean Seas Guide for Oil Tankers
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FOSFA (for Oils, Seeds and Fats)
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Prevention of Oil Spillage through Cargo Pumproom Sea Valves
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CHRIS Guide (USCG)
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Chemical Data Guide for Bulk Shipment by Water (Condensed Chris)
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MSDS for particular cargo carried
-
Chemical Tank Cleaning Guide
Our detail pages contain somewhat larger lists of resources where you may find more useful information.
Main Info pages!
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