Static electricity is generated by friction that occurs between different materials during relative motion. Electrostatic charges
can then accumulate in materials which are poor conductors of electricity or which are good conductors but are insulated. If
two such bodies with accumulated static electricity charges are brought close together, and if the difference of potential is
great enough, the accumulated charge will jump between them.
Anyone who has received a mild shock when touching a
doorknob after walking across a carpeted room has experienced such a phenomenon. In such cases the individual has become
charged by friction between the carpet and the soles of the shoes and the potential accumulated in the body is discharged to
the knob. This, though annoying, is harmless. But if a strong discharge of static occurs as a spark where a flammable
atmosphere is present, there is a risk of igniting the atmosphere.
The primary concern about static electricity is the possibility of generating an incendive spark within a flammable atmosphere.
Inerting a tank can prevent the existence of a flammable gas mixture so that no hazard will exist.
Static electricity can be generated due to the passage of a liquid through a hose or pipeline, and
turbulence within a tank. In normal circumstances the charge generated is released instantaneously to earth (the ship's
structure) because the liquid conducts it, and design features of cargo tank internals will avoid its build up. The problem is
greater on very large tankers equipped with large individual tanks than it is on the smaller size of chemical carriers with
extensive subdivision and multiple cargo tanks.
Problems from static electricity are most likely to arise when loading cargoes known as static accumulators, often highly
refined petroleum products. It is important, quite apart from cargo quality requirements, to make sure
that lines which have been flushed with water have been thoroughly drained and that the bottom of the tank is dry before
starting to load a static accumulator cargo.
At the initial stage of the loading operation, it is important that the loading rate is limited. Until the bottom longitudinals and
tank suction are covered, loading speed of the liquid in the pipeline should not exceed a linear velocity of I metre per second
(m/s), which corresponds to the following loading rates:
Pipeline diameter Loading rate
200 mm 115 cubic metres per hour
150 mm 65 cubic metres per hour
loomm 30 cubic metres per hour
Thereafter, loading may be increased to a maximum pipeline speed of 7 m/s. Experience indicates that hazardous potentials in
respect of static electricity do not occur if the velocity is below 7 m/s. However, where well documented experience
demonstrates that higher velocities have been safely used, an appropriately higher limit than 7 m/s may be employed.
We have summarized below the process of static electricity may happen in a chemical tanker in 5 different steps :
1. An electrostatic charge is generated in the liquid as it flows turbulently through the loading pipeline into the ship'~tank.
In
most liquids the charge is released instantaneously to earth* because the liquid conducts it.
2. But in some cases, the charge is accumulated in the liquid because the liquid has a low electrical conductivity. Such liquids
are called static accumulators, and are generally found among more highly refined products. An electrostatic field is formed
inside the tank.
3. A non-bonded projecting object, or something introduced into the tank, can become a potential electrode or spark
promoter, collecting the charge from the liquid.
4. When close enough to an earth* the spark promoter instantaneously releases its charge in a spark through the atmosphere
of the tank.
5. Such a spark will almost certainly have enough energy to ignite a flammable vapour. In chemical tanker operations, a
flammable atmosphere may be unavoidable.
Following detail pages explain all liquid chemical hazards & precautionary measures while carrying at sea.
- Controlling sources of static electricity onboard chemical tanker
- Accumulation of electrostatic field, charge relaxation and surface voltage inside a ships tank
- Toxicology and associated hazards onboard chemical tankers
- Hazards of vapour given off by a flammable liquid while carrying at sea
- Reactivity of various noxious liquid chemicals
- Most corrosive chemicals carried onboard chemical tankers
- Posoning hazards & first aid treatment
- What is putrefaction process of liquid chemicals ?
- Specific gravity,Vapour pressure and boiling point,Electrostatic charging & measuring Viscosity
- General precautions onboard chemical tankers
- Mooring precautions onboard chemical tankers
- Berth precautions onboard chemical tankers
- Cold weather countermeasures, avoiding electric storms
- Restriction on using radio equipments and other mobile devices in cargo working areas
- Handling precautions for carcinogens or cyanide-like substances
- Handling precautions for Benzene & Methanol
- Securing cargo tank lids and required safety precautions
- Means of access (gangways or accommodation ladders) safety precautions
- Preparations for hot work and safety precautions
- Safe method of gas freeing after a tank cleaning onboard chemical tankers
- Precautions against static electricity
- Handling precautions for nitrogen from shore station
- Cargo tank entry safety precautions
- Ship to ship transfer safety precautions
- How to deal with chemical fire onboard ?
Following reference publications provide useful guidance and international regulations for carrying hazardous chemicals at sea.
- SOLAS (latest consolidated edition)
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MARPOL – 73/78 (latest consolidated edition)
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BCH / IBC Code
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International Safety Guide for Oil Tankers and Terminals (ISGOTT)
-
Tanker Safety Guide (Chemicals)
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Ship to Ship Transfer Guide (Petroleum)
-
Safety in Oil Tankers
-
Safety in Chemical Tankers
-
IMDG Code
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Supplement to IMDG Code (Including MFAG and Ems)
-
SOPEP
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Clean Seas Guide for Oil Tankers
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FOSFA (for Oils, Seeds and Fats)
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Prevention of Oil Spillage through Cargo Pumproom Sea Valves
-
CHRIS Guide (USCG)
-
Chemical Data Guide for Bulk Shipment by Water (Condensed Chris)
-
MSDS for particular cargo carried
-
Chemical Tank Cleaning Guide
Our detail pages contain somewhat larger lists of resources where you may find more useful information.
Main Info pages!
Home page |||
Chemical hazards |||
Cargo planning & Stowage |||
Cargo loading
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Cargo documents
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Safe stability
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Cargo care
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Preparation for unloading
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Inert gas systems
|||Gas freeing
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Nitrogen handling
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Chemical handling Safe practice
|||Handling equipments
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Cargo & Ballast pumps
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Cargo tanks
|||Tank cleaning
|||Special cargoes
|||Spills emergencies
|||Fire protection
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