Cargo tanks of a chemical tanker are required to be provided with
venting systems to prevent both over and under pressurisation of the tank. Two types of
venting system are specified by the Code, namely “open” and “controlled”.
Open tank venting system – An open venting system is for cargoes which are of little or
no flammable or toxic hazard.
Controlled tank-venting system – Controlled venting systems are required to be fitted
in all tanks carrying cargoes emitting harmful or flammable vapours. Each tank must be
fitted with pressure/vacuum valve to relieve over-pressure or under-pressure.
Venting of cargo tanks during cargo transfer or cargo related operations must be carried out in accordance with applicable
international, national, port and terminal regulations. On chemical tankers the general rule is that the primary venting system is PV valves and the secondary means are cargo tanks pressure monitoring system.
Tank vent system outlets are located at a safe distance from all areas
where personnel who are not involved in cargo work may be present, to ensure that toxic vapours are diluted to a safe level of
concentration before they can reach such an area. The safe distances specified depend on the severity of the toxic hazard. In all
cases the principles described in the IMO Codes will have been met by the ship's design.
Fig: Pressure-vacuum valves on a chemical tanker
Fig: Cargo tanks venting arrangement- SOLAS requirement
The cargo tank venting system should be set for the type of operation to be performed. Cargo vapour displaced from tanks
during loading or ballasting should be vented through the installed venting system to atmosphere, except when return of the
vapour to shore is required. The cargo or ballast loading rate should not exceed a rate of vapour flow within the capacity of
the installed system.
In the case of ships fitted with a venting system which is common to several tanks, it is important to remember that vapours (or
liquid in the event of overfill) may pass through the venting system from one tank into another, and thereby cause
contamination of cargo or tank atmosphere.
Fig:Chemical tanker pressure vacuum valves
A required level of maintenance and inspection will be necessary to ensure the cleanliness of the venting system, and in
particular of the P/V valves, high velocity valves and devices to prevent the passage of flame into cargo tanks. Particular
attention should be given to the possibility of flame screens becoming blocked by dirt, freezing water, or vapour condensation
from certain chemical cargoes - e.g. those with high melting points or liable to polymerise -since blockage can severely
jeopardise tank integrity.
What is a Pressure-vacuum valve (P/V valve)?
A valve which keeps the tank over pressure or under
pressure within approved, limits. P/V valve provides for the flow of the small volumes of
vapour, air or inert gas mixtures caused by thermal variations in a cargo tank. The vacuum
valve opens if the pressure in the tank falls below a pre-set level – to draw air into the tank
through a flame trap. In the event of over-pressure, two release valves open to ensure
that venting is upwards and at high velocity, to avoid concentrations of gas on deck.
The IBC Code requires the ship to be able to return vapours of most toxic chemicals to shore. When a tank is connected to a
vapour return line, it is important to keep a safe pressure balance between the ship and shore. The vapours should be
evacuated fast enough to keep the pressure in the tank below the set opening pressure of any pressure relief valve in the tank
venting system; IMO guidelines recommend a maximum tank pressure of 80% of the set pressure. It is thus critically
important clearly to agree in advance with the shore terminal management what the liquid loading rate and the pressure at the
vapour connection will be, and to plan how they will be controlled.
Liquid should not be permitted to enter the vapour return line. If liquid gets into the vapour line it will cause the cross section
available for the flow of vapour to be reduced, as a result of which the pressure inside the tank can rise rapidly. Loading
should be suspended until the pressure is released, and the presence of liquid dealt with.
Connection of hoses intended for vapour transfer to manifold flanges of pipelines for liquid transfer is prevented by a stud
permanently fixed between two bolt holes in the presentation flange of the ship's vapour return manifold. The stud will fit into
a corresponding additional hole in the flange of the shore vapour hose. Vapour connections should also be identified by
painting and stencilling in a standard way .
Fig: Vapour manifold presentation flanges, orientation and labelling
Related Info:
PV valves operation, maintenance& safety precautions
Cargo unloading operation safety precautions
Liaison between ship and shore Ship to ship transfer guideline using VEC systems
Preparation for cargo operation
Preparing a cargo tank atmosphere
Various stages of cargo loading operation
Cargo care during transit
A wide range of instrumentation may be fitted on a modern chemical tanker. Only an outline is given here, providing
guidance on the safe and efficient operation of the equipment.
Cargo instruments
Liquid level gauges
Temperature monitoring
Overflow control
Oxygen analysers
Vapour detection
Alarm circuit Gas freeing
Pre-cleaning /washing of cargo tanks
Final cleaning of cargo tanks prior loading
Tank cleaning and posoning hazards
Testing of tanks and cargoes
Practical tank cleaning methods for various noxious liquid cargo
Special tank cleaning method
Determining proper tank cleaning by acid wash method
Supervision of all tank cleaning and gas freeing operations
Disposal of tank washings, slops and dirty ballast - safe method
Poisoning and required first aid treatment onboard
After tank cleaning gas freeing safety guideline
for chemical tankers
Checklist for handling dangerous liquid chemicals in bulk
Preparations prior allowing personnel into cargo tanks / enclosed spaces
How to rescue injured or unconscious person from enclosed spaces
Preparations for hot work and safety precautions
Cargo tank damage during pigging operations
Fig: Modern Chemical tanker tank instrumentation
It should be borne in mind that individual ship has got own characteristics and limitations may involved handling various chemical cargoes . The master and all personnel in all cases must be aware of cargo/ship information that has been given and comply with relevant safety procedures.
Reference publications
- Equipment Manufacturers Instruction Manuals
-
MARPOL – 73/78 (latest consolidated edition)
-
International Safety Guide for Oil Tankers and Terminals (ISGOTT)
-
CFR 33 parts 125 to 199
-
Ship to Ship Transfer Guide (Petroleum)
-
MSDS for particular cargo carried
-
Chemical Tank Cleaning Guide
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